For trains in sunlight I generally use Tv and set the shutter speed between 1/320 and 1/500, depending on the speed and direction of the train. I then set ISO at a level that will give me ~ f8, which is usually around 160 iso.
I generally use center weighted average metering. Canon's evaluative metering doesn't seem to work that well for me. Could be I'm just used to center weighted from my old 35mm cameras.
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